PSV vs Napoli | Prediction | UEFA Champions League | 21/10

The kick off for the match between PSV and Napoli will take place at 20:00 (UK time) - Tuesday, 10/21 - at the Philips Stadion. This clash of the 2025/26 UEFA Champions League looks very promising!

Before placing your bets on this match, check out the full analysis including predictions for PSV vs Napoli. We also highlight the most interesting odds and markets with a high chance of winning. Providing today’s best free tip to help you make informed and profitable betting decisions.

APWin predictions for PSV vs Napoli

With odds already released by major bookmakers, our experts have crunched the numbers and dissected the key match data. Find our value-packed prediction for this encounter below:

After a thorough assessment of the primary betting markets, APWin analysts have identified bets with strong value potential.

PSV preview

PSV has played 2 matches in the UEFA Champions League so far, with 0 wins, 1 draws, and 1 losses. This results in an average of 0.5 points per match.

In the 2025/26 season, the team has recorded 8 wins, 2 draws, and 2 losses. PSV's attack has scored 31 goals, 2 of them in the league, which gives an average of 1 goals per league match and 2.58 goals per match across the entire season.

Joey Veerman is the team’s top scorer with 4 goals, while Ivan Perišić leads the team in assists with 5. Defensively, PSV has conceded 4 goals in the league (an average of 2) and 17 goals throughout the entire season (an average of 1.42 over 12 matches).

Napoli preview

In 2 UEFA Champions League matches, Napoli has recorded 1 wins, 0 draws, and 1 losses, with an average of 1.5 points per game.

In the 2025/26 season, the team has 6 wins in 9 matches. The team has scored 14 goals, 2 of them in the UEFA Champions League (an average of 1 goals per match), with Kevin De Bruyne being the team's top scorer with 3 goals and Leonardo Spinazzola providing 2 assists.

Defensively, Napoli has conceded 3 goals in the league and 10 in the 2025/26 season overall, resulting in an average of 1.11 goals conceded per match.

Head to head: PSV vs Napoli

Review the head-to-head record between the teams, featuring key data to support your match prediction.

PSV

Home

WWDWD

VS

Napoli

Away

LWWLW

OverallHome / Away

Points & Results

• 0.50
  PPG
  1.50
• 0%
  Wins
  50%
• 0%
  First to Score
  50%

Goals Scored & Conceded

• 1
  Scored/game
  1
• 2
  Conceded/game
  1.50
• 1.10
  xG
  0.80
• 1.73
  xGA
  2

Trends

• 100%
  Both Score
  50%
• 0%
  Clean Sheet
  0%
• 0%
  Failed to Score
  50%

Access all match stats for PSV vs Napoli

Where to watch PSV vs Napoli live?

Check out the live stream of PSV vs Napoli below and follow the match in real time.