PSV vs Napoli: predictions, odds, head to head, where to watch, and more!

The kick off for the match between PSV and Napoli will take place at 20:00 (UK time) - Tuesday, 10/21 - at the Philips Stadion. This clash of the 2025/26 UEFA Champions League looks very promising!

Before placing your bets on this match, check out the full analysis including predictions for PSV vs Napoli. We also highlight the most interesting odds and markets with a high chance of winning. Providing today’s best free tip to help you make informed and profitable betting decisions.

APWin predictions for PSV vs Napoli

With odds already released by major bookmakers, our experts have crunched the numbers and dissected the key match data. Find our value-packed prediction for this encounter below:

APWin Prediction

Over 2.5 Goals

After a thorough assessment of the primary betting markets, APWin analysts have identified bets with strong value potential.

👉 Our prediction is: PSV to win the 1st half

Our top betting tip for the PSV vs Napoli match is PSV to win the first half. While the half-time market is not one of the more well-known betting markets, it often offers better value odds than wins over 90 minutes.

We see this value in PSV, which has been in impressive form at home and regularly gets out to quick starts. They should have a favourable matchup against Napoli, who have had their share of struggles of late.

PSV preview

PSV has played 2 matches in the UEFA Champions League so far, with 0 wins, 1 draws, and 1 losses. This results in an average of 0.5 points per match.

In the 2025/26 season, the team has recorded 8 wins, 2 draws, and 2 losses. PSV's attack has scored 31 goals, 2 of them in the league, which gives an average of 1 goals per league match and 2.58 goals per match across the entire season.

Joey Veerman is the team’s top scorer with 4 goals, while Ivan Perišić leads the team in assists with 5. Defensively, PSV has conceded 4 goals in the league (an average of 2) and 17 goals throughout the entire season (an average of 1.42 over 12 matches).

Heerenveen

PSV

PSV

Volendam

Liverpool

PSV

NAC Breda

PSV

PSV

Napoli preview

In 2 UEFA Champions League matches, Napoli has recorded 1 wins, 0 draws, and 1 losses, with an average of 1.5 points per game.

In the 2025/26 season, the team has 6 wins in 9 matches. The team has scored 14 goals, 2 of them in the UEFA Champions League (an average of 1 goals per match), with Kevin De Bruyne being the team's top scorer with 3 goals and Leonardo Spinazzola providing 2 assists.

Defensively, Napoli has conceded 3 goals in the league and 10 in the 2025/26 season overall, resulting in an average of 1.11 goals conceded per match.

Napoli

Cagliari

Roma

Napoli

Napoli

Qarabag

Napoli

Atalanta

Bologna

Napoli

Head to head: PSV vs Napoli

Review the head-to-head record between the teams, featuring key data to support your match prediction.

PSV

Europe - UEFA Champions League

Form	Last 5	PPG
Overall	D L L	0.5
Home	L L	0
Away	D	1

Stats	Overall	Home	Away
Win %	0%	0%	0%
Goals	3	4	2
Scored	1	1	1
Conceded	2	3	1
Both Teams to Score	100%	100%	100%
Without Conceding	0%	0%	0%
Failed To Score	0%	0%	0%
1st to Score	0%	0%	0%
xG	1.1	1.36	0.84
xGA	1.73	1.98	1.47

Napoli

Europe - UEFA Champions League

Form	Last 5	PPG
Overall	W L L	1.5
Home	W	3
Away	L L	0

Stats	Overall	Home	Away
Win %	50%	100%	0%
Goals	2.5	3	2
Scored	1	2	0
Conceded	1.5	1	2
Both Teams to Score	50%	100%	0%
Without Conceding	0%	0%	0%
Failed To Score	50%	0%	100%
1st to Score	0%	100%	0%
xG	0.8	1.31	0.29
xGA	2	1.1	2.9

Access all match stats for PSV vs Napoli

Where to watch PSV vs Napoli live?

Check out the live stream of PSV vs Napoli below and follow the match in real time.

Published on 21 October 2025, at 10:29 Last updated on 5 December 2025, at 19:01

Gustavo Porto

Author

Journalist since 2016, post-graduate during pandemic, and in love with football since child. Sporting was always part of the Gustavo's life, be practicing, watching, making the coverage, and a few years prae here, betting.